Organic contaminants in water serve as nutrients or shelters for microorganisms. Water disinfection removes or deactivates these contaminants.
Water contamination typically comes from human activities. Human waste or pharmaceutical pollutants make their way into water sources through sewers. Industrial process water used by manufacturing, chemical plants, the energy industry and other applications gets discharged back into rivers and streams. Agriculture fosters natural nutrient enhancement, which increases the volume of nitrates and phosphates in water and encourages algae growth. All of these activities bring an array of bacteria, acids, salts, toxic metals, nitrates and suspended sediment into the water supply.
Steps to treat water (on both a municipal and industrial level) include screening debris, odor control, filtering sedimentation, pH control, coagulation and flocculation, disinfection and other steps including fluoridation.
This article focuses on disinfection, which is primarily accomplished using chemicals such as sodium hypochlorite. It identifies the strengths and weaknesses of the disinfectant, and it highlights some of the challenges that pumping equipment must address to effectively handle sodium hypochlorite.
A Look at Sodium Hypochlorite
Discovered in the late 1700s, sodium hypochlorite (NaOCl) is widely used for water purification, odor removal and water disinfection. Among the many alternatives used for water disinfection (hydrogen peroxide, chlorine, bromine and other halogens) NaOCl appears to offer a reliable mix of low cost, ease of use, safety and effectiveness in areas where water is not excessively turbid. It is a clear, slightly yellowish oxidizing agent with a characteristic odor. To kill germs, NaOCl oxidizes molecules in the cells of the bacteria. It breaks down the cell walls of most germs and makes their cells unable to function.
When NaOCl dissolves in water, two substances form: hypochlorous acid (HOCl), which plays a role in oxidation, and the hypochlorite ion (OCl-), which is the key to disinfection. The pH, which is an indicator of the acid or alkaline condition of water, is an important variable to control in disinfection processes.
The pH is measured on a scale of 0 to 14. Acidic conditions have a pH less than 7. Alkaline (or base) conditions are greater than 7. The pH balance is present when the fluid hits the neutral number for the specific application (and each treatment plant’s applications vary depending on the water being treated).
Commonly used chemicals for neutralization include NaOCl, sodium hydroxide, sulfuric acid and sodium bisulfate, among others. The oxidizing aspect of NaOCl generates oxygen bubbles at ambient temperatures. These bubbles can accumulate in pump suction lines and cause a loss of prime, which causes numerous issues including vapor locking in some pumps.
Pumping Requirements for Sodium Hypochlorite
More than 90 percent of water disinfection applications require low pressure pumps, typically in the 30 to 50 psi range. Disinfection applications do not require extreme accuracy, and pumps that can deliver within 2 to 3 percent accuracy are sufficient. Flow ranges for pumps follow the volume of water to be disinfected in the plant, as well as the characteristics of the local water. Typically, a range of 5 to 10 milliliters of NaOCl dosed for every 20 liters of water is sufficient to disinfect disease-causing organisms.
Pressure, accuracy and flow capacity do not present unique challenges for sodium hypochlorite applications. The key issue for pumps is the ability to address vapor locking.
The design of rotary gear pumps is suited for NaOCl applications. Gear pumps distribute a constant volume of fluid with each revolution, and flow rates are easily altered by variable speed drives (VSDs). The gear set draws liquid into and through the pump. As the gears turn, liquid passes through the gear tips and the inner housing to the discharge side of the pump. Gear pumps can handle a wide range of volume flows and fluid viscosities, and they are suited to handle wide temperatures ranges.
Specific “hypo pump” configurations on gear pumps increase reliability and sealing capability in a manner that is well suited to handle NaOCl or other entrained gasses.
When it comes to the wetted components of a pump for these applications, polyvinylidene fluoride (PVDF) composite fluoropolymer materials provide excellent chemical resistance. Sealless magnetically driven pumps ensure no leakage and no emissions, which is critical when dealing with corrosive and highly volatile substances like NaOCl.