Do Pumps Require Less NPSH on Hydrocarbons?
The extensive application of pumps to hydrocarbon services in the first half of the 20th century produced numerous observations that centrifugal pumps handling liquid hydrocarbons were able to operate satisfactorily with less NPSH available than when pumping water, and the NPSHr was less when pumping lighter hydrocarbons than when pumping heavier hydrocarbons.
Based on tests and field observations, the Hydraulic Institute (2) and the Natural Gas Processors Suppliers Association (3) published correction factors (based on suction pressure and the specific gravity of the pumpage) to use as multipliers for water NPSHr.
Stahl & Stepanoff (4) expanded understanding of the subject by investigating NPSHr from the standpoint of the thermodynamic properties of the pumpage, proposing the reason for hot water NPSHr being less than cold water NPSHr, and suggesting that 70deg F propane would have the same NPSHr as 300 deg F water.
Salemann (5) performed NPSH tests on water, butane, benzene, kerosene, gasoline and Freon‑11 at various temperatures, showing the correction to cold water NPSHr not as a factor, but as a fixed head subtraction.
Whistler (6) explained the reason for the different NPSHr when pumping various liquids, and confirmed that the reduction in NPSHr was not a factor, but a fixed head (in feet or meters) to be subtracted from the (cool) water NPSHr. His equation, which can be used to calculate the NPSHr correction from thermodynamic properties, is as follows:
Δh = (2.31/SGL)[(P1-P2)/(T1-T2)](V)(SGV/SGL)(F + H/100Cp)
Where (in U.S. units):
Δh = Subtraction from cool‑water NPSHr, ft
SGL = Specific gravity of liquid
SGV = Specific gravity of vapor (relative to water)
(P1-P2)/(T1-T2) = Slope of vapor pressure curve, psi/deg F
V = Volume percent of vapor to liquid in imp. eye
F = Slope of initial vaporization, deg F/wt. % vapor
H = Latent heat of vaporization, BTU/lb
Cp = Specific heat of liquid, BTU/lb‑deg F
V is the percent volume of vapor in the impeller eye to produce a 3 percent head drop. Whistler suggests two as a reasonable number. If the pumpage is a single component, F = 0.
The Hydraulic Institute (2) and NGPSA (3) subsequently replaced their factor charts with a chart that provided a fixed correction to NPSHr, based on pumpage thermodynamic properties. Those charts indicate a larger V factor than the two suggested by Whistler.
With great 20‑20 hindsight, we can now explain this phenomenon.
As stated earlier, the NPSHr for a centrifugal pump is defined as the amount of NPSHa when the head drops 3 percent. The head drops because a certain volume of gas has formed in the impeller eye. Liquids that are closer to their critical pressure will flash to a smaller volume of gas, because the density of the gas is closer to the density of the liquid. A liquid right at its critical pressure could all flash to a gas without affecting pump head (or anything else). (There would actually be no flashing.)